Forecast for Houston: Air Quality Improving

Multi-layered strategies and high-tech equipment focus on the region

Even with a growing population and industrial base, the Houston region is making headway in air quality improvements. Over the years, the TCEQ has compiled an array of strategies and high-tech equipment to tackle air quality problems. Here is an update of those efforts, as well as a progress report on an ambitious project to update the health screening values for a number of key chemicals.

In this story:
Large Industrial Hub
Guidelines Protect Health
Getting Results
Sidebar: Health Screening Levels Take Shape

An infrared imaging camera, which can see emissions invisible to the naked eye, is one of the technologies the TCEQ has
                                       deployed in the Houston area to improve air quality.

Multi-layered strategies and high-tech equipment focus on the region Armed with advanced technology capable of detecting emissions, two TCEQ investigators made a discovery last year that surprised even the veterans in their field.

Jason Harris of the Houston regional office recalls that he and a co-worker were conducting fence-line monitoring near the town of Shoreacres, east of Houston. They were using an infrared imaging camera that can find air pollution invisible to the human eye.

With the camera, called the GasFindIR, Harris and his colleague saw significant amounts of emissions spewing from separator equipment at a natural gas production facility.

A follow-up inspection showed that the industrial site had a permit to release 25 tons per year of volatile organic compounds (VOCs) and had been reporting emissions of only 4.7 tons. Testing showed that in reality an estimated 386 tons a year of VOCs were escaping.

The TCEQ began enforcement proceedings, and the company owner installed a vapor recovery unit, which lowered emissions to an allowable level.

Harris attributes the discovery and quick resolution to the infrared camera, which the agency uses on a regular basis to assist in locating unauthorized or previously unknown emissions from industrial plants and marine vessels. With this technology, environmental regulators can identify emissions that once were difficult—if not impossible—to detect.

But this unique camera is just one approach to addressing air quality issues.

Houston's impressive skyline reflects the fact that the city is the fourth largest in the U.S. The area's population
                                       and industrial base continue to grow. Photo copyright by iStock.com/John Zellmer

Houston not only has the ongoing problem of ground-level ozone—the area is in nonattainment of the federal 8-hour ozone standard. But, there is also an abundance of industrial facilities emitting various kinds of contaminants. One notable example is benzene, a well-documented carcinogen that is a building block for many products, such as packaging, compact disks, and gasoline.

Benzene and other air toxics, like 1,3 butadiene, are not regulated directly under the National Ambient Air Quality Standards, but rather as hazardous air pollutants and through the state's New Source Review permitting program.

The Environmental Protection Agency is required to control 188 hazardous air pollutants, or air toxics. In sufficient concentrations, these pollutants could potentially cause a wide variety of adverse health effects.

To track this category of pollutants, the TCEQ has assembled an array of advanced monitoring tools. The agency also pursues multiple strategies to get results, including soliciting industry cooperation to find and reduce emissions.

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Large Industrial Hub

Harris County and its neighboring counties are home to eight petroleum refineries, three of which are listed among the 10 largest in the United States. Also more than 150 chemical facilities in the area provide products for the domestic and international markets.

Yet, even with steady growth—in terms of people, traffic, and industry—the region continues to make progress cleaning the air.

Chart: Annual Averages of Benzene. Of the 25 air toxics monitors in the Houston area, the majority have seen declining
                                       benzene levels the last two to three years. When 2007 data analysis is complete by mid-year, there may be only two monitors
                                       still exceeding the effects screening level. The new ESL for benzene, established in October 2007, is 1.4. parts per billion.

"With state regulations and enforcement activity, the levels of nitrogen oxides have fallen 57 percent and VOCs by 38 percent since 2000," said David Schanbacher, the chief engineer at the TCEQ. "This represents a total reduction of 675 tons per day of these smog-forming pollutants."

Air quality also continues to improve, says Schanbacher, because the TCEQ is aggressively targeting specific air toxics, such as benzene. Some of the monitoring tools helping to pinpoint these emissions in the Houston area include:

Infrared cameras. With the technology of the GasFindIR camera, which was developed for the military, TCEQ investigators can view emission plumes not visible to the naked eye. The agency owns six cameras. Besides two at the Austin headquarters used for field monitoring, there are two in the Houston regional office, and one each in the Corpus Christi and Midland regions.

Through an agreement with the U.S. Coast Guard, TCEQ investigators are now able to conduct infrared-camera observations of facilities along the Houston Ship Channel from Coast Guard vessels. This way, state investigators can get much closer to facilities on the water.

The infrared camera has also been dispatched on aerial surveys of industrial sites. In 2005, the camera helped identify more than 7,000 tons per year of ozone-forming emissions, including benzene. Those emissions have since been eliminated.

For the public to understand how the agency intends to use data generated by these cameras, the TCEQ has developed a protocol (look under "GasFindIR Use Protocol").

Mobile monitoring. The TCEQ deploys up to eight mobile monitoring vans to conduct monitoring for different pollutant types, sampling upwind and downwind of specific facilities to identify pollution sources. This practice is helpful when there is no stationary monitor in the proximity or when a stationary monitor has identified key pollutants in a highly industrialized area. In a cluster of facilities, it can be difficult to pinpoint a pollution source with just a stationary monitor. Agency vans drive outside a company's fence line, with monitors positioned according to the wind direction, to pinpoint sources of elevated emissions.

Differential absorption lidar (DIAL). This mobile monitoring unit combines infrared and ultraviolet laser technology to scan industrial facilities and measure emissions from sources such as storage tanks, flares, and cooling towers. After a five-week trial last year, the TCEQ is reviewing DIAL monitoring data to determine whether calculation methods used to estimate emissions result in the underrepresentation of some sources that are difficult to monitor.

These various types of mobile equipment complement a broad array of stationary monitors in the region, some of which calculate hourly averages of emissions day and night. The TCEQ and partners in local government and industry operate stationary air samplers that together make up one of the largest monitoring networks in the world. The system includes monitors capable of triggering e-mail alerts when concentrations spike, so that the TCEQ and its partners can quickly look for the emissions source.

The TCEQ is paying special attention to tugboats, towboats, and barges working on the Houston Ship Channel to determine
                                       the source of benzene emissions. A monitoring station near the Lynchburg Ferry reports pollutant concentrations every hour.

In another development with the Coast Guard, the maritime agency is helping the TCEQ pinpoint emissions from vessels traveling the Houston Ship Channel. The TCEQ hosts data from several industry-sponsored monitors, one of which is an automated gas chromatograph at the Lynchburg Ferry, where the ship channel meets the San Jacinto River. Using real-time data, the monitor issues an alert when it detects elevated concentrations of benzene.

The Coast Guard checks wind direction and provides a radar picture of the tugboats and towboats that were in the vicinity at the time of the concentration spike.

Because the state does not regulate marine vessels in transit, the TCEQ assigns its pollution prevention team, which has no enforcement authority, to contact the tug, tow, and barge owners to gather information on what the barge was carrying, and where it was traveling to and from. Through this approach, the TCEQ may be able to determine whether barges carrying benzene products are contributing to benzene levels in the air.

American Waterways Operators has agreed to work with the TCEQ on this project. The TCEQ, along with the Louisiana Department of Environmental Quality, has also assisted this organization with creating a guidebook of best management practices to help reduce inadvertent emissions from tank barges.

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Guidelines Protect Health

The TCEQ established the Air Pollutant Watch List to identify locations in which specific pollutants have been measured
                                       at levels that could cause adverse short-term or long-term health problems. Currently, 14 locations are listed; of those,
                                       five are in Harris, Galveston, and Brazoria counties. The remainder can be found in the counties of Bastrop, Bowie, Cass,
                                       Dallas, El Paso, Jasper, Jefferson, and Nueces. The agency uses the Watch List to raise awareness and encourage emission reductions.
                                       For more information, see www.tceq.state.tx.us/goto/airwatch.

The TCEQ uses scientific data to establish health-protective levels of exposure for air pollutants. These "effects screening levels" are also known as ESLs (see "Health Screening Levels Take Shape.")

The agency relies on ESLs and state regulatory standards to designate areas for the Air Pollutant Watch List and to set enforceable industrial air permit limits.

When an air quality monitor measures trends that exceed an ESL, the TCEQ places the surrounding area on the Watch List for stricter inspections, monitoring, enforcement, and permitting reviews.

Of 14 monitoring locations on the Watch List in Texas, five are in Harris, Galveston, and Brazoria counties. In just the Houston-Galveston Watch List areas, the annual averages for benzene were 20 percent to 48 percent lower in 2006 than in 2005. There were further improvements in 2007. One additional area in Galveston County was removed from the Watch List in 2007 after monitoring data showed sustained benzene reductions.

When monitored levels fail to decline, the agency takes additional steps, such as aggressive use of state-of-the-art monitoring equipment, to find and implement controls on previously underestimated or unknown emissions.

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Getting Results

An important part of the TCEQ's strategy has been to work in cooperation with industry, and those efforts are paying off on the east side of Houston.

In the Milby Park and Manchester neighborhoods, voluntary agreements obtained with local companies resulted in lower levels of 1,3 butadiene at the nearest downwind monitor—a drop of 75 percent annual average concentrations from 2004 to 2007.

This occurred after a series of meetings with large firms that had been identified as potential sources. The resulting agreements established specific timelines for the facilities to reduce specific emissions and/or implement additional controls, such as flare gas recovery systems and improved controls on flare and wastewater emissions. Companies also agreed to install their own fence-line monitoring and to use infrared cameras to find leaks.

From 2005 to 2007, benzene levels at the Lynchburg Ferry monitor measured a 52 percent reduction. The agency used monitors and the infrared camera to target potential sources in this heavily industrialized area, which includes barge operations, tank facilities, chemical plants, and petroleum refineries. TCEQ enforcement activities, industrial emission-reduction agreements, and a collaborative effort with area industries to identify and control emissions all contributed to this achievement.

To the naked eye, nothing appears amiss at this tank facility in Nederland. But the lens of an infrared imaging camera
                                       (right) tell a different story-hydrocarbons escaping into the atmosphere of East Texas. This new camera technology is helping
                                       to advance mobile monitoring.

In the process of focusing on pollution sources, owners of industrial facilities often find they ultimately save money by locating leaky equipment. In the Shoreacres investigation, once the emissions problem was resolved, the company was no longer losing valuable raw product. In these cases, the pollution control equipment pays for itself in short order.

"With all the resources devoted to the Houston area, we can say there has been significant progress in air quality, including air toxics. But much remains to do," said Schanbacher. "That is why the TCEQ continues to look for ways to protect the environment and reduce pollution. We do this relying on health-based data and state-of-the-art monitoring tools to prioritize our investigations and regulatory actions."

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Health Screening Levels Take Shape

Revised guidelines for air quality will better protect public health

Toxicologists at the TCEQ are working on a project to update the health screening values for key chemicals—air pollutants that are closely tracked by many of the air quality monitors in Texas or are frequently permitted.

Among these are toxic air pollutants—chemicals that are known or suspected to cause cancer or other serious health problems in sufficient concentration and exposure.

The project is part of an ambitious re-examination of the agency's "effects screening levels," or ESLs. These levels are chemical-specific air concentrations established to protect the public's health. ESLs are established for air pollutants that are not regulated by federal ambient air quality standards.

The agency's ESLs are set well below levels that would cause adverse health effects. When monitored levels of a chemical exceed its ESL, that triggers further evaluation of actual risk and, if appropriate, emissions reductions. ESLs play a leading role in evaluating air monitoring data, setting emission limits in air permits, and determining safe cleanup levels during remediation projects.

TCEQ management decided in 2003 to update the 30-year-old ESLs. That decision started agency toxicologists on a two-year review of all known methods of deriving health-protective values. Their resulting methodology won the approval of a scientific peer review.

In 2006, after two rounds of public comments, the TCEQ completed new guidelines for developing ESLs. For chemicals that may cause cancer, the agency adopted a cancer-risk level of 1 in 100,000, which is the midpoint in the Environmental Protection Agency's range of 1 in 10,000 to 1 in 1,000,000.

Under the TCEQ risk level, if 100,000 people were continuously exposed for a lifetime to a concentration of a carcinogen equal to the ESL, there would theoretically be one case of cancer—in addition to the current U.S. rate for all cancers of 30,000 to 40,000 for every 100,000 people. Exposure at the 1-in-100,000 level is unlikely to cause adverse health effects in the general public. The TCEQ rejected the 1-in-10,000 level as not sufficiently health-protective.

Examining the ultra-low 1-in-1,000,000 risk level led to conclusions that using this risk level would result in unenforceable violations at most air toxics monitors. For example, the TCEQ is barred by federal law from setting emission standards for cars and trucks. Yet at many monitors across the country, including those in rural and suburban areas of Texas, benzene exceeds the 1-in-1,000,000 risk level due to vehicle emissions alone.

By the end of 2007, the toxicology team had completed nine ESLs, including one for benzene, that meet the health-protective 1-in-100,000 risk level. Another 10 ESLs, which include 1,3 butadiene, were submitted to the public for comments in January 2008. Work is under way on 11 more ESLs.

Once completed, the new ESLs take effect immediately.

The ESLs for benzene and 1,3 butadiene have drawn considerable attention because both are known human carcinogens. Industrial facilities in Harris County produce more of these two compounds than any other location in the country.

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